Search results for "water purification"

Ti-based robust MOFs in the combined photocatalytic degradation of emerging organic contaminants.

2022

Photocatalysis process is a promising technology for environmental remediation. In the continuous search of new heterogeneous photocatalysts, metal–organic frameworks (MOFs) have recently emerged as a new type of photoactive materials for water remediation. Particularly, titaniumbased MOFs (Ti-MOFs) are considered one of the most appealing subclass of MOFs due to their promising optoelectronic and photocatalytic properties, high chemical stability, and unique structural features. However, considering the limited information of the reported studies, it is a hard task to determine if real-world water treatment is attainable using Ti-MOF photocatalysts. In this paper, via a screening with seve…

Performance of a membrane-coupled high-rate algal pond for urban wastewater treatment at demonstration scale

2020

[EN] The objective of this study was to evaluate the performance of an outdoor membrane-coupled high-rate algal pond equipped with industrial-scale membranes for treating urban wastewater. Decoupling biomass retention time (BRT) and hydraulic retention time (HRT) by membrane filtration resulted in improved process efficiencies, with higher biomass productivities and nutrient removal rates when operating at low HRTs. At 6 days of BRT, biomass productivity increased from 30 to 66 and to 95 g.m(-3).d(-1) when operating at HRTs of 6, 4 and 2.5 days, respectively. The corresponding nitrogen removal rates were 4, 8 and 11 g N.m(-3).d(-1) and the phosphorous removal rates were 0.5, 1.3 and 1.6 g P…

Low cost-sensors as a real alternative to on-line nitrogen analysers in continuous systems.

2009

This paper is focused on the evaluation of the applicability of low-cost sensors (pH and ORP) versus nutrient analysers for controlling biological nitrogen removal in WWTPs. A nutrient removal pilot plant located in Carraixet WWTP (Valencia, Spain) that is equipped with a significant number of nutrient analysers and low-cost sensors was used. The relations between reliable, cheap on-line sensors such as pH and ORP (located in anaerobic, anoxic and aerobic zones) and the nitrification/denitrification processes are provided. The nitrification process can be evaluated by measuring the pH difference between the first and last aerobic zones. The denitrification process can be evaluated by measur…

Iron-based metal-organic framework: Synthesis, structure and current technologies for water reclamation with deep insight into framework integrity.

2021

Water is a supreme requirement for the existence of life, the contamination from the point and non-point sources are creating a great threat to the water ecosystem. Advance tools and techniques are required to restore the water quality and metal-organic framework (MOFs) with a tunable porous structure, striking physical and chemical properties are an excellent candidate for it. Fe-based MOFs, which developed rapidly in recent years, are foreseen as most promising to overcome the disadvantages of traditional water depolluting practices. Fe-MOFs with low toxicity and preferable stability possess excellent performance potential for almost all water remedying techniques in contrast to other MOF…

Quantification of kinetic parameters for heterotrophic bacteria via respirometry in a hybrid reactor

2010

Over the last decade new technologies are emerging even more for wastewater treatment. Among the new technologies, a recent possible solution regards Moving Bed Biofilm Reactors (MBBRs) that represent an effective alternative to conventional processes. More specifically such systems consist in the introduction of plastic elements inside the aerobic reactor as carrier material for the growth of attached biomass. Recently, one of the mostly used alternatives is to couple the Moving Bed Biofilm Reactor (MBBR) process with the conventional activated sludge process, and the resulting process is usually called HMBBR (Hybrid MBBR). In the MBBR process the biofilm grows attached on small plastic el…

Adsorption of a dye on clay and sand. Use of cyclodextrins as solubility-enhancement agents.

2007

Abstract Laboratory-scale studies were aimed at elucidating the physico-chemical aspects on the removal process of crystal violet (CV) from waters and solid substrates. The laponite clay (RD) and sand were chosen for the double aim at investigating them as CV adsorbents for water treatment and as substrates which mime the soil components. Sand is very effective in removing CV from waters. The cyclodextrins (CDs) were exploited as solubility-enhancement agents to remove CV from the solid substrates. They are powerful solvent media because they extract the CV from sand forming water-soluble CV/CD inclusion complexes and do not show affinity for sand. Optimum performance was shown by the modif…

Simulation and control of dissolved air flotation and column froth flotation with simultaneous sedimentation.

2020

Abstract Flotation is a separation process where particles or droplets are removed from a suspension with the aid of floating gas bubbles. Applications include dissolved air flotation (DAF) in industrial wastewater treatment and column froth flotation (CFF) in wastewater treatment and mineral processing. One-dimensional models of flotation have been limited to steady-state situations for half a century by means of the drift-flux theory. A newly developed dynamic one-dimensional model formulated in terms of partial differential equations can be used to predict the process of simultaneous flotation of bubbles and sedimentation of particles that are not attached to bubbles. The governing model…

Modulating effects of humic acids on genotoxicity induced by water disinfectants in Cyprinus carpio

2005

The use of chlorinated disinfectants during drinking-water production has been shown to generate halogenated compounds as a result of interactions of humic acids with chlorine. Such chlorinated by-products have been shown to induce genotoxic effects and consumption of chlorinated drinking-water has been correlated with increased risk for cancer induction in human populations. The aim of this work was to test the potential genotoxic effects on circulating erythrocytes of the fish Cyprinus carpio exposed in vivo to well-waters disinfected with sodium hypochlorite (NaClO), chlorine dioxide (ClO2) or peracetic acid (CH3COO2H, PAA), in the absence or presence of standard humic acids (HA). The ef…

Titania Photocatalysts for Selective Oxidations in Water

2011

Heterogeneous photocatalysis by polycrystalline semiconductor oxides is an unconventional technology that has been mainly applied for the degradation of organic and inorganic pollutants in both the vapor and liquid phase. The application of photocatalysis in synthetic routes has also been researched in recent years, demonstrating its viability as an alternative route in organic chemistry. This work illustrates the main findings in the application of heterogeneous photocatalysis to the oxidation of organic compounds dissolved in water, free of any organic co-solvent. Two main aspects of the oxidative process have been studied: the first one is the partial oxidation of various mono-substitute…

Protein aggregates for water purification

Water pollution is the contamination of water bodies including lakes, rivers, oceans and it is a leading global risk factor for illness and death for people, plants and living organisms. A principal source of water pollution is industry, from which increasing amounts of toxic pollutants are released including heavy metals such as cobalt, lead and copper. Today various technologies for purifying contaminated water can be applied, a lot of them being typically expensive, ion specific and characterised by low efficiency. For these reason, the search of new biocompatible materials with increased capabilities is strongly needed.Protein aggregates have already revealed their potential as environm…